South-South Cooperation （SSC） on addressing climate change is an important part of global climate governance. China as a major advocate and promoter of SCC has been taking a leading role in the process，not only on finance contribution but also on actions. SCC on addressing climate change is a new thing with new challenges to developing countries，since they have used to receive support but not provide from outside for a long time. SCC may need some of the developing countries shift their traditional position to support providers. As to China，the challenges of this shifting including：Lack of top-level design of SCC on national level；Actions for SCC being in relatively primitive stage；The mechanism for SCC needing to be further refined，etc. Based on the analysis of the experience of industrialized countries in the field of international cooperation，this paper put forward recommendations and suggestions for the implementation of SSC in the future.