The average concentration of PM2.5 in China has gradually declined from 2008. Smog pollution in the Yangtze river delta and the pearl river delta has eased，but the Beijing-Tianjin-Hebei region remains the most polluted area in the country. The impact of industrial structure on haze pollution is mainly due to the significant differences of energy consumption in different industries. Based on GWR model，the impact of industrial structure on haze pollution shows significant spatial difference. Different areas of haze pollution are affected by industrial structure，and the specific affected industry is also different. For haze pollution is greatly influenced by industrial structure area，we can control haze pollution through the optimizing and upgrading the industrial structure，increasing the intensity of environmental regulation，changing the energy structure，and establishing the mechanism of polluting enterprises exit way.