It is great meaningful to investigate Contiguous Destitute Areas’ poverty alleviation policy implementation and its effect for optimizing poverty relief countermeasures and promoting poverty alleviation effect，then achieve the goal of eliminating poverty totally in Thirteen Five period. This report reinterpreted Contiguous Destitute Areas’ poverty from perspective of regional system of human-land relationship，raised a “People-Industry-Land”（PIL）Comprehensive Poverty Alleviation analysis frame，and constructed an evaluation indexes system for Contiguous Destitute Areas’ poverty relief policy implementation and effects，then，using it to evaluate and comparative analysis 6 Contiguous Destitute Areas’（Dabie Mountain Area etc.）policy implementation and effects by sorting out policies from 2011 and in-depth interviewing and surveying on village cadres and villagers. The results showed that lots of interviewees considered the policy implemented well and generally policy for “People” better than policy for “Land” and “Industry”，the conclusion indicated the poverty relief thought was people first，however，the general poverty alleviation effect was lower than expectation，and Wuling Mountain Area’s performance was relatively better than other 5 areas. Besides，there were 4 modes of PIL poverty relief exploration，such as Xianglong modes of education plus industry，Xiangxi Wei Village modes of Internet plus poor village，Xianfeng modes of “121 plus 3” and Guizhou practices of innovation of benefits coupling mechanism for poverty relief industry，and all of these modes and mechanism innovation was the practices of PIL poverty alleviation and also good for urging Contiguous Destitute Areas’ PIL comprehensive poverty alleviation.