The emergence of apprenticeships has a long history in China，in response to the emergence of the emerging markets as well as traditional apprenticeship in conducting process bottlenecks encountered. The Ministry of Human Resources and Social Security have carried out pilot work on new enterprise apprenticeships. Through the method of case study，this paper analyzes and demonstrates the trial process，action mechanism and effect of this emerging model with five pilot enterprises in Beijing as the focus. Research shows that the new apprenticeship system has a significant role in promoting the competitiveness of enterprises：the new apprenticeship system first changes the overall atmosphere of the organization through the construction of enterprise knowledge and culture，starts from the environment and further acts on internal capabilities，and realizes the competitiveness of enterprises through the transformation to dynamic capabilities. promotion and promotion. Enterprises play an important role in the process of implementing the new apprenticeship model. Recognizing the important impact of this new model on the competitiveness of enterprises will help both schools and enterprises to achieve good cooperation in the process and effective implementation of results.