After building a well-off society in an all-round way，the focus of government’s rural work will shift from winning the battle of poverty alleviation to promoting rural revitalization. Due to the unity of goals and values，the unity of policies and behaviors between education targeted poverty alleviation and rural revitalization，it has become an organic link between targeted poverty alleviation and rural revitalization in the Pearl River-Xijiang River Economic Belt probably. At present，in the process of the implementation of targeted poverty alleviation through education in the Pearl River-Xijiang River Economic Belt，the infrastructure construction of rural schools has been continuously improved，the rural education assistance mechanism has been initially established，the education and training mechanism for village personnel has been basically established，and the cultural literacy and skill level of rural personnel have been gradually improved，which has consolidated the organic connection between targeted poverty alleviation and rural revitalization in the Pearl River-Xijiang River Economic Belt However，in order to achieve the organic convergence of the two，we still need to deal with the following problems：to deal with the organic convergence of policies，ensure the stability of education support policies，resources and power input，find the work convergence point of education targeted poverty alleviation to boost rural revitalization，and face up to the differences in policies and objectives between education targeted poverty alleviation and rural revitalization. Therefore，we can promote the organic connection between education targeted poverty alleviation and rural revitalization from the implementation of rural education infrastructure construction project，rural backbone teacher construction project，rural education development leader training project，and rural agricultural workers’ vocational skills improvement project.