The comprehensive competitiveness index can measure the comprehensive strength of an enterprise，which is widely used at present. China’s baijiu making culture has a long history，and baijiu can be said to be the best carrier of China’s 5000 year culture. The evaluation of the competitiveness of Chinese baijiu enterprises is helpful for enterprises to understand their own situation，so as to give full play to their comparative advantages and better guide the development of baijiu enterprises. On the basis of introducing the background and significance of compiling the competitiveness index of Chinese baijiu enterprises，the general report constructs the competitiveness index of Chinese baijiu enterprises from six dimensions：brand realistic value，capital operation ability，marketing ability，human resource ability，product development（innovation）ability and corporate social responsibility. According to the results of index calculation，the ranking of top 200 enterprises in China is given and the distribution of top 200 enterprises in baijiu production and marketing provinces is described. At the same time，the ranking of top 100 enterprises under six categories of indicators is given and corresponding analysis is given. Finally，the characteristics of top 10，20 and 50 enterprises with comprehensive competitiveness are analyzed.