From the perspective of non-agricultural industrial structure and secondary and tertiary industrial structure，the paper respectively examines the trend of China’s urban industrial structure evolution from 1995 to 2016，and analyzedits driving factors and impact on urban per capita development. The study found that：（1）There is an obvious trend of gradual decline in the rate of urban industrialization，and urban non-agricultural industrial structure exist obvious differences between city types；（2）The urban post-industrialization speed shows a relatively obvious u-shaped trend，and there are obvious differences between urban types in the secondary and tertiary industrial structure.（3）The initial industrial structure and urban types have significant influence on the evolution of non-agricultural industrial structure and secondary and tertiary industrial structure.（4）Change of the non-agricultural industries has a significant positive influence on per capita GDP growth，whilechange of difference between the tertiary industry and the secondary industry has a significant negative influence on it.